SUBJECT : Fugitive Emissions
and the Carcinogens 5-1
The clean air act of 1990 was signed by President
Bush in November of 1990. This was the toughest version yet. It
addressed many subjects that included :
- To bring from 7 to 189 the number of toxic
chemicals that will be controlled, aiming at a reduction of 90% by
the year 2000.
- The phasing out of chlorinated fluorocarbons
(CFCs) and carbon tetrachloride by 2000 and the banning of
hydrochloroflurocarbons (HCFCs) by 2030
The first 41 categories of chemicals and compounds
became law in November 1992. Sixty three more were added in November
1994, another sixty three in 1997, and the restin January 1, 2000.
Hazardous organics were thethe first to be scrutinized. Benzene, coke
oven emissions, and ethylene oxide sterilizers will probably follow
shortly after.
Plants will be required to install the best
available air pollution control devices described as "Maximum
Achievable Control Technologies"
(MACT).
MACT will be defined as "the best available controls [for plants
of the same type], taking cost into account". New plants will
have to match the control levels reached by the lowest emitters in
their category, while existing plants will have to meet a target
based on the average emissions from 12% of their competitors most
tightly controlled plants.
In this paper I have noted the chemicals that are
presently on both the Carcinogen and Fugitive Emissions lists. The
compounds on these lists should be sealed with two (dual) mechanical
seals to prevent their escaping to the atmosphere and violating the
applicable restrictions or possible harming personnel in the
area.
The first list is for the fugitive emission
chemicals . You'll note that I have included some uses for these
compounds along with the names.
Fugitive emissions are defined
as those emissions not caught by a capture system which are often due
to equipment leaks, evaporative processes and windblown
disturbances.
The list of 189 Toxic compounds includes
:
- Acetaldehyde * ... Manufacturing acetic acid
and acetic anhydride.
- Acryilic Acid * ... A monomer for polyacrylic
and other acrylic polymers
- Acrylonitrile * ... Plastic fibers and grain
fumigant.
- Allyl chloride ... Resins,
adhesives
- Aniline * ... Rubber, dyes, explosives
petroleum refining herbicides, fungicides.
- Benzene ... Styrene, insecticides, solvent,
paint remover, rubber cement, gasoline anti- knock
additive.
- Benzyl Chloride ... Dyes, photograph
developer, pharmaceuticals.
- 1,3-Butadiene ... Rubber, latex
paints.
- Caprolactam * ... Plastics, film coatings,
paint.
- Carbon Tetrachloride ... Refrigerants,
propellants, metal degreasing, production of semi-
conductors.
- Chlorine ... Plastics, refrigerants,
propellants, solvents, water treatment, sewage treatment, pulp and
paper.
- Chlorobenzene ... Solvent.
- Chloroform ... Refrigerant, propellants,
plastics, dyes, drugs, solvent.
- Cresols/ cresylic acid ... Coatings, metal
cleaning, oil additive, pesticide
- Cumene ... Production of phenol and
acetone.
- Diethanolamine * ... Liquid detergent, paint,
cutting oils, shampoo, cleaners, polish
- Dimethyl Phthalate ... Plastacizer, resins,
rubber, solid rocket propellant.
- Epichlorohydrin * ... Epoxy resins, rubber,
solvent, resins for paper industry.
- Ethyl Benzene ... Styrene production,
solvent.
- Ethyl Chloride ... Manufacture of tetraethyl
lead. Solvent for fats, oils, resins, waxes
- Ethylene Dichloride * ... Vinyl chloride,
finish removers, penetrating agents.
- Ethylene Glycol * ... Anti-freeze, brake
fluid, lacquers, paints, adhesives.
- Ethylene Oxide * ... Manufacture of ethylene
glycol, petroleum demulsifier.
- Formaldehyde * ... Resins, preservative, dye,
reducing agents.
- Glycol Ethers
- mono- and di-ethers of ethylene
- diethylene glycols
- triethylene glycols
- Hydrochloric Acid * ... Ore reduction,
pickling, metal cleaning, cleaning.
- Hydrofluoric acid * ... Glass etching,
aluminum production, cleaning castings.
- Maleic Anhydride ... Resins, pestacides,
permanent press resins, fumaric acid manufacture.
- Methanol (methyl alcohol) * ... Anti freeze,
dye, resins, chemical synthesis.
- Methyl Methacrylate ... Monomer for resins,
impregnate for concrete.
- Methylene Chloride ... Paint remover, solvent,
degreaser, textile coating.
- Phenol * ... Resins, solvent for refining,
lubricating oil.
- Phosphorus ... Manufacture of phosphoric
acid.
- Phthalic Anhydride ... Hardener for resins,
dyes, chlorinated products.
- Propylene Oxide * ... Glycols, surfactant,
detergents, synthetic lubricants.
- Styrene ... Foam, radiator leak
stopper.
- Styrene Oxide ... Organic
intermediate.
- Perchloroethylene ... Dry cleaning solvent,
drying agent for metals.
- Titanium Trichloride ... Reducing agent,
stripping agent.
- Toluene ... Aviation gasoline, adhesive
solvent, explosives, plastics.
- Trichloroethylene ... Metal degreasing,
extraction solvent, dyeing, dry cleaning.
- Vinyl Acetate ... Latex paints, paper coating,
adhesives, safety glass.
- Vinyl Bromide ... Synthesis.
- Vinyl Chloride ... Polyvinyl chloride,
adhesive for plastics.
- Xylenes ... Aviation gasoline, protective
coatings, rubber cements, lacquers.
- Compounds based on :
- Arsenic
- Beryllium
- Cadmium
- Chromium
- Cobalt
- Cyanide
- Lesad
- Manganese
- Mercury
- Nickel
- Selenium
- Polycyclic Organics
- Coke oven emissions
- Radionuclides
- Radon
- Asbestos
- Fine Mineral fibers
* dissolves in water, so you should be able to use
water as a flush or as a barrier fluid between two mechanical seals.
Check with your technical people to be sure.
In the United States, cancer is the second most
common cause of death. Section 262 of Public law 95-622 of November
9,1978 stipulates that the Secretary of the Department of Health and
Human services shall publish an annual report which contains a list
of all substances which either are known to be carcinogens or may
reasonably be anticipated to be carcinogens and to which a
significant number of persons in the United States are
exposed.
The comprehensive list was published in the 1989
summary. I have extrapolated those chemicals that we encounter in the
petrochemical industry and left out those that are pretty much
limited to the medical profession. If you are interested in allowable
exposure limits or have any other questions about the noted chemicals
contact the U.S. Department of Health and Human Services for the
Fifth Annual Report On Carcinogens Summary 1989 NTP
89-239.
Known carcinogens are defined as, "those
substances for which the evidence from human studies indicates that
there is a casual relationship between the exposure to the substance
and human cancer." The list includes :
- 4-Aminobiphenyl ... No commercial use in the
United states. Was used as a rubber antioxidant and as a reagent
for detecting sulfates.
- Arsenic and certain Arsenic compounds ...
Pestacides, wood preservatives, alloying additive, glass and non
ferrous alloys.
- Asbestos ... Insulation, gasketing, packing,
coatings, plastics, textiles, friction materials.
- Benzene ... Solvent, gasoline
additive.
- Benzidine ... Dyes in textile and
paper.
- Bis(chloromethyl)ether and technical grade
Chloromethyl Methyl Ether ... Synthesis of plastic and ion
exchanger resins.
- Chromium and certain Chromium compounds ...
Stainless steel, pigment, Medical, plating, wood treatment,
paint
- Mustard Gas ... Biological studies,
weapons.
- 2-Naphthylamine ... Dyes, rubber. Used only
for research purposes.
- Thorium Dioxide ... Nuclear, flame spraying,
welding electrodes, high temperature ceramics.
- Vinyl Chloride ... Plastics, wrapping film,
phonograph records, credit cards floor tiles.
Here are some substances which may reasonably be
anticipated to be carcinogens. Defined as, "those for which there is
a limited evidence of carcinogenicity in humans or sufficient
evidence of carcinogenicity in experimental animals".
- Acrylonitrile ... Synthetic fibers resins,
plastics, elastomers.
- 2-Aminoanthraquinone ... Dyes, paints
plastics, rubber, printing inks.
- o-Aminoazotoluene ... Pigments, coloring oils,
wax polishes.
- 1-Amino-2-methyllanthraquinine ... Dye for
synthetic fibers as well as animal furs.
- Amitrole ... Herbacide, now limited to non
crop applications.
- o-Anisidine Hydrochloride ...
Dyes.
- Benzotrichloride ... Plastics, dyes and
pigments.
- Beryllium and certain Beryllium compounds ...
Alloys for areo space applications, ceramic additive to glass and
plastic.
- 1,3-Butadiene ... Synthetic rubber, tires,
nylon carpet backing, latex adhesives
- Cadmium and certain Cadmium compounds ...
Coating and plating.
- Carbon Tetrachloride ... Production of Freon
11 & 12, de-greasing, plastic and resin
production.
- Chlorendic Acid ... Flame retardant,
foams.
- Chlorinated Parraffins (C12, 60% Chlorine) ...
Lubricant additive, flame retardant, rubber
production.
- Chloroform ... Production of flurocarbon,
refrigerant, heat transfer medium in fire
extinguishers.
- 3-Chloro-2-methylpropene ... Fumigant, textile
additive, plastics.
- 4-Chloro-o-phenylenediamine ... Hair dye,
photographic chemicals.
- C.I. Basic Red 9 Monohydrochloride ... Dye for
textiles, leather printing inks, china clay.
- p-Cresidine ... Dyes.
- Cupferron ... A reagent to seperate tin from
zinc and copper and iron from other metals.
- DDT ... Insecticide. In the U.S. it used only
under Public Health Service supervision.
- 2,4-Diaminoanisole Sulfate ... Fur, acrylic
fiber, polyster, wool , cotton and hair dye.
- 2,4Diaminotoluene ... Polyurethane,
dye.
- 1,2-Dibromo-3-chloropropane ... Soil
fumigant.
- 1,2-Dibromoethane (EDB) ... Gasoline
anti-knock additive, pestacide
- 1,4-Dichlorobenzene ... Space deodorant
(toilets, rooms) germacide
- 3,3'-Dichlorobenzidine and
3,3'-Dichlorobenzidine Dithydrochloride ... Pigments.
- 1,2-Dichlorethane ... Component of leaded
fuel, production of vinyl chloride.
- Dichloromethane (Methylene Chloride) ...
Solvent in paint removers, manufacture of vitamins, degreasing
agent.
- 1,3-Dichloropropene (Technical Grade) ...
Pesticides.
- Diepoxybutane ... Curing agent for
polymers.
- Di(2-ethylhexyl)phthalate ... Used to make
poly vinyl chloride.
- Diethyl Sulfate ... Surfacants, dyes,
agricultural chemicals.
- Diglycidyl Resorcinol Ether ... Liquid epoxy
resin.
- 3,3'-Dimethoxybenzidine ... Production of azo
dyes.
- 4-Dimethylaminoazobenzene ... To color
polishes and other wax products.
- 3,3'-Dimethylbenzidine ... Dye, chlorine test
kits.
- Dimethylcarbamoyl Chloride ... Dyes,
pestacide.
- 1,1-Dimethylhydrazine ... Propellant for
liquid fuel rockets.
- Dimethyl Sulfate ... Used to manufacture other
chemicals.
- Dimethylvinyl Chloride ... Organic
synthesis.
- 1,4-Dioxane ... Stabilizer in chlorinated
solvents.
- Direct Black 38 ... Dye
- Direct Blue 6 ... Dye
- Epichlorohydrin ... Epoxy resins.
- Ethyl Acrylate ... Paper coatings, emulsion
based polymers.
- Ethylene Oxide ... Manufacture of ethylene
glycol and polyster.
- Ethylene Thiourea ... Rubber, O-rings,
electroplating.
- Formaldehyde (Gas) ... Adhesives, chemical
production, medical.
- Hexachlorobenzene ... Pesticide
- Hexamethylphossphoramide ... Solvent for
polymers, de-icing additive for jet fuels.
- Hydrazine and Hydrazine Sulfate
...Agricultural chemicals, rocket fuel, oxygen scavanger in boiler
feed water.
- Hydrazobenzene ... Dye, additive to motor
oil.
- Kepone® (Chlordecone) ... Insecticide, no
longer used in the U.S.
- Lead Acetate and Lead Phosphate ... Drier in
paints and varnish, colorant in hair dyes.
- Lindane and other Hexachlorocyclohexane
Isomers ... Insecticidal treatment for wood, grain and live
stock.
- 2-Methylaziridine (Proplyleneimine) ... Paper,
textile, rubber.
- 4,4'-Methylenebis(2-chloroaniline) (MBOCA) ...
Curing agent.
- 4,4'-Methylenebis(N,N-dimethyl)benzenamine ...
Dye
- 4,4'-Methylenedianiline and its
Dihydrochloride ... Manufacture of polyisocynates and
isocyanates.
- Michler's Ketone ... Dyes and
pigments.
- Mirex ... Pesticide, fire
retardant.
- Nickel and certain Nickel compounds ....
Stainless and alloy steel.
- Nitrilotriacetic Acid ... Detergent, water
treatment.
- 5-Nitro-o-Anisidine ... Dye
- 2-Nitropropane ... Solvent, inks, paints
polymers.
- N-Nitrosodiethanolamine ... No commercial
use.
- N-Nitrosodiethylamine ... Stabilizer in
plastics, gasoline and lubricant additive.
- N-Nitrosodimethylamine ... Liquid rocket fuel,
solvent.
- p-Nitrosodiphenylamine ... Rubber,
dye.
- N-Nitrosopiperidine ... Epoxy
resin.
- 4,4'-Oxydianiline ... Production of polyimide
and poly(ester)mide resins.
- Polybrominated Biphenyls ... Flame retardant,
plastics.
- Polychlorinated Biphenyls ... Heat transfer
and hydraulic fluids.
- Polycyclic Aromatic Hydrocarbones, 15 listings
... Coal tar, roofing, creosote, asphalt.
- Benza(a)anthracene
- Benzo(b)fluoranthene
- Benzo(j)fluoranthene
- Benzo(k)fluoranthene
- Benzo(a)pyrene
- Dibenz(a,h)acridine
- Dibenz(a,j)acridine
- Dibenz(a,h)anthracene
- 7H-Dibenzo(c,g)carbazole
- Dibenzo(a,e)pyrene
- Dibenzo(a,h)pyrene
- Dibenzo(a,l)pyrene
- Indeno(1,2,3-cd)pyrene
- 5-Methylchrysene
- 1,3-Propane Sultone ... Detergents lathering
agents.
- Propylene Oxide ... Coatings and
adhesives.
- Saccharin ... Sweetening agent.
- Safrole ... Flavoring agent.
- Selenium Sulfide ... Shampoos.
- Sulfallate ...Herbacide.
- Tetrachloroethylene (Perchloroethylene) ...
Dry cleaning and textle production.
- Thioacetamide ... Replacement for hydrogen
sulfide in qualitative analysis.
- Thiourea ... Animal glue.
- Toluene Diisocyanate ... Polyurethane
foam.
- o-Toluidine and o-Toluidine Hydrochloride ...
Dyes and pigments.
- Toxaphene ... Insecticide
- 2,4,6-Trichlorophenol ... Wood preservative,
anti mildew.
- Tris(2,3-dibromopropyl)phosphate ... No longer
used in the U.S. .Was a flame retardant.
- Urethane ... No commercial use because of its
toxicity.
FUGITIVE EMISSIONS &
CARCINOGENS
Fugitive
emissions
- Acetaldehyde *
- Acryilic Acid *
- Acrylonitrile *
- Allyl chloride Aniline *
- Benzene
- Benzyl Chloride
- 1,3-Butadiene
- Caprolactam *
- Carbon Tetrachloride
- Chlorine
- Chlorobenzene
- Chloroform
- Cresols/ cresylic acid
- Cumene Diethanolamine *
- Dimethyl Phthalate
- Epichlorohydrin *
- Ethyl Benzene
- Ethyl Chloride
- Ethylene Dichloride *
- Ethylene Glycol *
- Ethylene Oxide *
- Formaldehyde *
- Glycol Ethers
- mono- and di-ethers of
ethylene
- diethylene glycols
- triethylene glycols
- Hydrochloric Acid *
- Hydrofluoric acid *
- Maleic Anhydride
- Methanol (methyl alcohol) *
- Methyl Methacrylate
- Methylene Chloride
- Phenol*
- Phosphorus
- Phthallic Anhydride
- Propylene Oxide*
- Styrene
- Styrene Oxide
- Perchloroethylene
- Titanium Trichloride
- Toluene
- Trichloroethylene
- Vinyl Acetate
- Vinyl Bromide
- Vinyl Chloride
- Xylenes
- Compounds based on :
- Arsenic
- Beryllium
- Cadmium
- Chromium
- Cobalt
- Cyanide
- Lesad
- Manganese
- Mercury
- Nickel
- Selenium
- Polycyclic Organics
- Coke oven emissions
- Radionuclides
- Radon
- Asbestos
- Fine Mineral fibers
Known
Carcinogens
- 4-Aminobiphenyl
- Analgesic mixtures containing
Phenacetin
- Arsenic and certain Arsenic
compounds
- Asbestos
- Azathioprine
- Benzene
- Benzidine
- Bis(chloromethyl)ether and technical grade
Chloromethyl Methyl Ether
- 1,4-Butanediol Dimethylsulfonate
(Myleran)
- Chlorambucil
- Chromium and certain Chromium
compounds
- Conjugated Estrogens
- Cyclophosphamide
- Diethylstilbestrol
- Dimethylnitrosamine
- Ethyleneimine
- Melphalan
- Methoxsalen with Ultra-violet A Therapy
(PUVA)
- 4,4'-Methylene
bis-(2-dichloroaniline)
- Methyl (chloromethyl) ether bis (Chloromethyl)
ether
- Mustard Gas
- 1-Naphthylamine
- 2-Naphthylamine
- 4-Nitrobiphenyl
- Thorium Dioxide
- Vinyl Chloride
- 2-Acetylaminofluorene
Believed to be
carcinogens
- 2-Acetylaminofluorene
- Acrylonitrile
- Adriamycin
- Aflatoxins
- 2-Aminoanthraquinone
- o-Aminoazotoluene
- 4-Aminobiphenyl
- 4-Aminodiphenyl
- 1-Amino-2-methyllanthraquinine
- Amitrole
- o-Anisidine Hydrochloride
- Aromatic Amines
- Auramine
- Benzotrichloride
- Beryllium and certain Beryllium compounds
.
- Bischloroethyl Nitrousourea
- Bromoprene
- 1,3-Butadiene
- Cadmium and certain Cadmium
compounds
- Carbaryl
- Carbon Disulfide
- Carbon Tetrachloride
- Chlorendic Acid
- Chlorinated Parraffins (C12, 60% Chlorine)
1-(2-Chloroethy)-3-cyclohexyl-1-nitrosourea (CCNU)
- Chloroform
- 3-Chloro-2-methylpropene
- 4-Chloro-o-phenylenediamine
- Chloroprene
- C.I. Basic Red 9 Monohydrochloride
- p-Cresidine
- Cupferron
- Dacarbazine
- DDT
- 2,4-Diaminoanisole Sulfate
- 2,4-Diaminotoluene
- Diazinon
- 1,2-Dibromo-3-chloropropane
- 1,2-Dibromoethane (EDB)
- 1,4-Dichlorobenzene
- 3,3'-Dichlorobenzidine and
3,3'-Dichlorobenzidine
- Dichlorovos
- Dithydrochloride
- 1,2-Dichlorethane
- Dichloromethane (Methylene
Chloride)
- 1,3-Dichloropropene (Technical
Grade)
- Diepoxybutane
- Di(2-ethylhexyl)phthalate
- Diethylstilboestrol
- Diethyl Sulfate
- Diglycidyl Resorcinol Ether
- 3,3'-Dimethoxybenzidine
- 4-Dimethylaminoazobenzene
- 3,3'-Dimethylbenzidine
- Dimethylcarbamoyl Chloride
- 1,1-Dimethylhydrazine
- Dimethyl Sulfate
- Dimethylvinyl Chloride
- 1,4-Dioxane
- Direct Black 38
- Direct Blue 6
- Epibromohydrin
- Epichlorohydrin
- Estrogens (Not Conjucated):
Estradiol-17ß
- Estrogens (Not Cojugated): Estrone
- Estrogens (Not Conjucated):
Ethinylestradiol
- Estrogens (Not Cojugated):
Mestranol
- Ethyl Acrylate
- Ethyl alcohol
- Ethylene Dibromide
- Ethylene Oxide
- Ethylene Thiourea
- Formaldehyde (Gas)
- Halothane
- Hexachlorobenzene
- Hexachlorophene
- Hexamethylphossphoramide
- Hydrazine and Hydrazine Sulfate .
- Hydrazobenzene
- Iron Dextran Complex
- Kepone® (Chlordecone)
- Lead Acetate and Lead Phosphate
- Lindane and other Hexachlorocyclohexane
Isomers
- Melphalan
- Methoxyflurane
- 2-Methylaziridine
(Proplyleneimine)
- 20-Methylcholanthrene
- 4,4'-Methylenebis(2-chloroaniline)
(MBOCA)
- 4,4'-Methylenebis(N,N-dimethyl)benzenamine
- 4,4'-Methylenedianiline and its
Dihydrochloride
- Metronidazole
- Michler's Ketone
- Mirex
- 1-Napthylamine
- 2-Naphthylamine
- Nickel and certain Nickel
compounds
- Nickel Sulfide
- Nitrilotriacetic Acid
- 5-Nitro-o-Anisidine
- Nitofen
- 4-Nitrobiphenyl
- Nitrogen Mustard Hydrochloride
- 2-Nitropropane
- N-Nitrosodi-n-butylamine
- N-Nitrosodiethanolamine
- N-Nitrosodiethylamine
- N-Nitrosodimethylamine
- p-Nitrosodiphenylamine
- N-Nitrosodi-n-propylamine
- N-Nitroso-N-ethylurea
- N-Nitroso-N-methylurea
- N-Nitrosomethylvinylamine
- N-Nitrosomorpholine
- N-Nitrosonornicotine
- N-Nitrosopiperidine
- N-Nitrosopyrrolidine
- N-Nitrososarcosine
- Nitrous Oxide
- Norethisterone
- 4,4'-Oxydianiline
- Oxymetholone
- Perbromoethylene
- Perchloroethylene
- Phenacetin
- PhenazopyridineHydrochloride
- Phenoxybenzamine Hydrochloride
- Phenytoin
- Phosphine
- Polybrominated Biphenyls
- Polychlorinated Biphenyls
- Polycyclic Aromatic Hydrocarbones, 15
listings
- Benza(a)anthracene
- Benzo(b)fluoranthene
- Benzo(j)fluoranthene
- Benzo(k)fluoranthene
- Benzo(a)pyrene
- Dibenz(a,h)acridine
- Dibenz(a,j)acridine
- Dibenz(a,h)anthracene
- 7H-Dibenzo(c,g)carbazole
- Dibenzo(a,e)pyrene
- Dibenzo(a,h)pyrene
- Dibenzo(a,l)pyrene
- Indeno(1,2,3-cd)pyrene
- 5-Methylchrysene
- Procarbazine Hydrochloride
- Progesterone
- 1,3-Propane Sultone
- Propiolactone
- Propylene Oxide
- Propylthiouracil
- Reserpine
- Saccharin
- Safrole
- Selenium Sulfide
- Sodium o-phenylphenate
- Streptozotocin
- Styrene (Vinyl Benzene)
- Sulfallate
- 2,3,7,8-Tetrachlorodibenzo-p-dioxin
(TCDD)
- Tetrachloroethylene
(Perchloroethylene)
- Thioacetamide .
- Thiourea
- Toluene Diisocyanate
- o-Toluidine and o-Toluidine
Hydrochloride
- Toxaphene
- Trichloroethylene
- 2,4,6-Trichlorophenol
- Tris(1-aziridinyl)phosphine
Sulfide
- Tris(2,3-dibromopropyl)phosphate
- Urethane
- Vinyl Bromide
- Vinylidene Bromide
- Vinylidene Chloride
- Yellow fatty dye
Occupational exposures
associated with a technical process that are known to be
carcinogenic
- Coke oven emissions
- Soots, tars and mineral oils
Delisted Chemicals
- Aramite®
- N,N-Bis(2-chloroethy)-2-naphthylamine
(Chlornaphazine)
- Cycasin
- Methyl Iodine
*Soluble in water, so you should be able to use
water as a flush or barrier fluid between two seals. Check with your
technical people
For information about my CD
with over 600 Seal & Pump Subjects
explained, click
here
Link
to the Mc Nally home page