Hard Face

HARD FACE H002

A good mechanical seal should run leak free until the carbon-graphite seal face wears away. This is the same way we decide if we are getting good life with our automobile tires. The tires should not go flat or the sidewalls “blow out”. The tire tread should wear at a rate that is consistent with our driving habits. Most people do not experience pre-mature tire failure, most tires wear out.

An inspection of your used seals will show that 85% or more of mechanical seals fail long before the faces wear out. The seal starts to leak and an inspection shows that there is plenty of wearable face visible. Some of these failures are caused by the wrong choice of seal face materials so we have to be knowledgeable about those materials that are available to us. The ideal hard face material would incorporate many features including the following:

  • Excellent corrosion resistance.
  • Self-lubricating.
  • High strength in compression, shear and tension.
  • High modulus of elasticity to prevent face distortion.
  • Good heat conductivity.
  • Good wearing characteristics (hardness).
  • Low friction.
  • High temperature capability.
  • Temperature cycling capability.
  • Easy insertion into a metal holder
  • Low coefficient of friction.
  • The ability to be molded in thin cross-sections.
  • Low cost.
  • Availability.
  • Low shrinkage.
  • Easily identifiable

Needless to say all of these characteristics are not available in the same face material. The idea is to get as many of them as you can in a properly chosen face combination.

With just a few exceptions, seal companies purchase hard face materials from outside vendors. Be sure the face component you chose is identified by material, type and grade so that you can check out the “physicals”. Some companies change the generic name of the material to confuse you. Make sure you know exactly what you are purchasing or you will never be able to trouble shoot a seal failure caused by a wrong material selection.

At the end of this article you will find a chart labeled: HARD FACE MATERIALS“. This chart lists the typical physicals for some of the most common hard face materials used in the mechanical seal industry. Most of the information was supplied by the Pure Carbon Company of St. Mary’s, Pennsylvania. Use these numbers only as a guide. Individual manufacturers use different testing methods and express the results in different metric and imperial units. I have also listed some of the hard face manufacturers so that you can contact them directly for test results, latest specifications, newer materials, etc.

Some additional information you should know about the materials listed in the attached chart:

Reaction bonded silicon carbide

  • Reaction bonded silicon carbide is produced by adding molten silicon to a mixture of silicon carbide and carbon. A reaction between the silicon and carbon bonds the structure while the excess silicon metal fills the majority of the pits left in the resultant material. There is almost no shrinkage during the process.
  • The silicon content is about 8% to 15%. High pH chemicals such as caustic can attack this grade of silicon carbide.
  • As of this writing carbon/ graphite vs. reaction bonded silicon carbide has been demonstrated to have the best wear characteristics of all the possible face combinations.
  • Reaction bonded silicon carbide is difficult to insert into a metal holder so it is usually supplied in a solid rather than a composite configuration.
  • There are many manufacturers of reaction bonded silicon carbide. The following chart shows some of them.
COMPANY
DESIGNATION
Carborundum
KT
BNFL
Refel
Coors
SC-2
Norton
HD-630
Pure Carbon
PS-9242
  • ESK, Shunk and Hoechst of West Germany are also manufacturers of reaction bonded silicon carbide .
    • Reaction bonded silicon carbide has proven to be more chip resistant than the sintered version
    • Avoid the following chemicals when using reaction bonded silicon carbide :
      • Calcium, Sodium or Potassium Hydroxide*
      • Nitric Acid *
      • Green Sulfate Liquor *
      • Hydrofluoric Acid
      • Caustics and strong acids
      • Most high pH chemicals

* Results vary with temperature and concentration.

The above chemicals can leach the silicon out of the silicon carbide leaving a weakened, hard matrix that can act like a grinding wheel against the softer carbon face.

Self sintered silicon carbide (sometimes called direct sintered or pressure less sintered)

  • This material begins as a mixture of silicon carbide grains and a sintering aid which is pressed and subsequently sintered as its name implies. Unlike reaction bonded SiC there is no free silicon present. These direct sintered materials have no metal phase and are therefore more resistant to chemical attack.
  • There are two grain shapes available to the manufacturer. Alpha (hexagonal structure) and Beta (cubic structure). There does not appear to be any difference in the chemical resistance, wear or friction of these two grain shapes.
  • These self-sintered materials will not be attacked by most process chemicals.
  • In the following box you will find some of the bigger manufacturers of self sintered silicon carbide:
COMPANY
DESIGNATION
Carborundum
SA-80
General Electric
Sintride
Kyocera
SC-201
  • Sintered silicon carbide is almost impossible to shrink into a metal holder because of the differences in manufacturing and molding tolerances.
  • Self-sintered silicon carbide carries a slight price premium compared to the reaction bonded version.
  • Although the preferred seal face material it is sometimes too brittle for some designs.

Siliconized graphite

  • The manufacturing process uses a permeable form of carbon graphite that is reaction sintered in silicon at elevated temperature. This forms an outer layer of silicon carbide on the graphite base.
  • A resin impregnate is added to increase the density.

Tungsten Carbide

  • Cobalt and nickel are the common binders. Each is susceptible to selective chemical attack of this metallic binder that will leave a skeletal surface structure of tungsten carbide particles.
  • Galvanic corrosion can take place between a passivated stainless steel shaft or seal face holder and the active nickel in the nickel base tungsten carbide seal face. This can be a real problem in caustic and other high pH fluids. The temperature at the seal face is higher than the temperature of the sealing fluid so the attack takes place quicker.
  • The metallic binders in tungsten carbide are also subject to galvanic attack near copper, brass or bronze.
  • Tungsten carbide is easy to insert into a metal holder so it is the most common material used in metal bellows and other hard face composite designs.

Here are some additional thoughts about hard seal faces:

  • Many sales people promote two hard faces running against each other as the ideal face combination for slurry and similar services. Keep in mind that solids cannot penetrate between seal faces unless they open. Seal faces are lapped to a flatness of less than one micron (three helium light bands) and as long as they stay in contact solids are filtered out. Here are some of the main disadvantages of using two hard faces in a seal application:
    • Higher cost compared to using carbon as a seal face.
    • If either face is “out of flat” it is almost impossible for the faces to lap themselves back together again.
    • Carbon graphite provides an additional lubricating film if you are sealing a poor or non lubricating fluid. It should be noted that many fluids fall into that category. It takes a film thickness of at least one micron at operating temperature and face load to be classified as a lubricating fluid.
    • Carbon graphite can easily be inserted into a metal holder.
    • In the event the equipment is “run dry” carbon-graphite is self-lubricating.
    • Use two solid hard faces in the following applications:
      • If you are sealing hot oil or almost any hot hydrocarbon. Most oils coke between the seal faces and can pull out pieces of carbon causing fugitive emissions problems.
      • If the product tends to stick the faces together.
      • If the product you are sealing is an oxidizer that will attack all forms of carbon, including black O-rings. Oxidizing chemicals are listed in another section of this manual.
      • Halogens can attack all forms of carbon. These chemicals include:
        • chlorine
        • fluorine
        • bromine
        • astintine
        • iodine
      • If you are pumping a slurry and you cannot keep the two lapped faces together by flushing, suction recirculation, a large diameter stuffing box or some other method usually employed to seal a large percentage of solids.
      • If nothing black is allowed in the system because of a possible color contamination of the product you are pumping.
      • Some deionized (DI) water applications can attack any form of carbon.
      • Plated or coated faces can “heat check” and crack due to the differential expansion of the coating and the base material.
      • PV factors as a design tool are unreliable because carbon is sensitive to “P” but not to “V”.
      • Water can cause cracking problems with both 85% and 99.5% ceramic. The cracking mechanism is not fully understood, but hydrogen embrittlement is suspected as the main cause. Cracks have been observed after seven to eight temperature cycles.

Unfilled carbon should be your first choice for a material to run against the above mentioned hard faces. Use an unfilled carbon in all applications except in those applications that require two hard faces and:

  • Cryogenic and dry running applications require a special carbon with an embedded organic to release the graphite.
  • Hot oil, if the seal has to meet fugitive emission standards.

HERE IS THE HARD FACE MATERIAL CHART I MENTIONED

Hard face Material

Hardness

Elastic Modulus E

Tensile Strength

Expansion

Conductivity

Density

Tempt. limit

Coeff. of friction

Mohs

GN/m2

MN/m2

µm/mK

Watts/m°K

mg/mm3

°C(a)

vs. Carbon

Gray cast iron

5

100

200

10

45

7.2

200

Hastelloy “B”

6

230

1300

18

45

8.9

800

M-2 Tool steel

7

200

2000

11

25

8.2

500

Niresist

4

100

400

18

15

7.4

500

316 Stainless

4

200

600

16

16

8

600

440C Stainless

5

200

800

10

25

7.8

600

Stellite

7

220

1000

14

15

8.4

1000

T/C – Cobalt

8

600

1400

4

100

15

400

0.07

T/C – Nickel

8

600

600

5

90

15

250

0.07

Ceramic 85%

8

200

150

5

12

3.4

1400

0.07

Ceramic 99.5%

8

350

250

7

25

3.9

1700

0.07

SiC Alpha Sintered

9.7

400

250

4

130

3.1

1000

0.02

SiC Reaction Bonded

9.7

400

250

4

150

3.1

1000

0.02

(a) Severe oxidation in air, or significant loss of hardness, or changed microstructure.

Hard Face  Material

Vickers

N/mm2

Watts/
m°C

Gm/cc.

°C(a)

Siliconized graphite

PE-8148

2000

16

50

1.95

232

Reaction Bonded

PR9242

2400

365

145

3.08

1372

Reaction Bonded

plus graphite PG9723

152

153

2.8

538

Alpha sintered

PS-10070

3000

400

130

3.1

1649

PS-10138

3000

407

130

3.1

1649

Category

Posted

  • On February 15, 2018